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The only downside to this high-performance material has been that it requires cooling, which can be costly. In a recent study, however, Newman and his graduate student assistant, Lingtao Liu, discovered a way to optimize the material so that it can operate at room temperature without requiring cooling. This will reduce cost and improve performance of the entire cell network.
To understand how this works, let’s first look at what happens during a call. An antenna at the top of a cell phone tower receives the signal and sends it down to be processed by filters, which distinguish one phone call from another.
“They need a very precise filter to listen to each particular channel in a very busy network,” Newman says. “The better the quality of those filters, the more cell phones a tower can support. The number of dropped calls also declines as quality goes up.”
The first step Newman’s group made was to choose the right starting material. Filter materials are composed of oxide ceramics, similar to those used to make decorative pots in your home. Typically, Newman says, oxide bonds do not have angular rigidity. Instead, they act like a room full of bowling balls.
“If you stood on them, you’d fall right through because the bowling balls slide right past each other,” Newman says.
As microwaves pass through the filter, atoms in the filter material vibrate against each other and the signal loses energy. But if certain chemicals are substituted, the material becomes stronger. No one knew why until now.
Newman explains that a special kind of bond is occurring that acts like Tinker Toys rather than bowling balls. “Some of the electrons in the inner shells, those that typically do not take part in bonding, transfer from one atom to the other to form rigid structures,” Newman says. The technical term for this is directional d-electron bonding. It’s similar to the covalent bonds that make diamonds so hard, and it’s what makes certain materials ideal for use in the filters.
This understanding allowed Newman and Liu to choose an appropriate starting material. Next, they investigated additives that are used to keep the filter’s frequency locked on a particular channel and not drift with temperature.
The scientists found that chemicals containing electrons with a magnetic component made the best additives.
“We can apply a magnetic field to the filters to keep the groups of electrons from vibrating and flipping over to the opposite direction, losing energy in the process,“ Newman explains. When this is done, the filter performance jumps to record high levels.
The work that led to identifying this mechanism will appear in the journal Physical Review Letters on Jan. 4, 2013. In a follow-up study that will appear in Applied Physics Letters on Dec. 24, Newman’s team showed that this material could be used in practical applications without needing to be cooled off, unlike previous materials.
In addition to cell phone base stations, the new and improved material has potential to be used in the area of security and defense.
“We’ve already started to give them to defense contractors who are going to try and use them for listening beyond our borders. Right now, the enemy thinks we can only hear so far away, but not if we use super high-performance materials,” Newman says.
Newman holds the Lamonte H. Lawrence Chair in Solid State Science, a position funded by a gift from ASU alumnus Lamonte H. Lawrence and his wife, Regina. Lawrence is the founder of Lawrence Semiconductor Research Laboratory, a Tempe-based company. The chair position supports cutting-edge research in the area of materials science, including research fellowships.
“Nate has been building a great relationship with Mr. Lawrence and the team at Lawrence Semiconductor,” says Josh Friedman, vice president of strategic philanthropy in the ASU Foundation for a New American University. “And in addition to his research achievements, he is leading what is becoming an internationally significant annual conference on epitaxy. He has also been using his lab to engage others across the university, and has even provided opportunities for high school students to get involved with research.”
Written by Allie Nicodemo, Office of Knowledge Enterprise Development